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Loki:4am. Not too early that everything is completely dead and hushed, but early enough to creep around the town in silence.
Bruce:5am. The new beginning is almost upon him. He’s been waiting for it for so long.
Clint:6am. Up as early as possible, earlier than normal people are. He wants to make the most of every day, and he never knows what each new one will behold.
Nick:7am. Awake at the most humane early point. He wants to get everything done, and wants to start that as soon as possible.
Thor:10am. The sun is high in the sky, and the life has long come out. Thor prefers it when everything is lively.
Coulson:Midday. The day is halfway over, but most people are only just getting started with the day by now. They’re finally busy in what they’re doing.
Pepper:1pm. The time she gets off work for lunch, and can have a relax before going back to being hard at work again.
Sam:4pm. The sun is dipping low in the sky, so the shadow of his wings cast shadows across the horizon.
Peggy:5pm. The first time she’ll get off work, and can finally relax and actually do exactly what she wants.
Darcy:8pm. The liveliest point of the night, where everyone is getting ready for either a new night spent out or a new day. Darcy does both of these things.
Jane:9pm. The sun has just set, and the stars are just coming out.
Natasha:10pm. So dark and mysterious, but there is still light and noise and life at this time. It’s maybe the most interesting point of the day.
Steve:11pm. It’s the eleventh hour, the day has been going for so long, and it’s almost over. It’s almost a relief.
Tony:Midnight. He works best and concentrates more when there’s no activity outside. He also secretly prefers being alone for a while.
Bucky:2am. The graveyard hours are dark, quiet, and lifeless, but still have the promise of a new beginning.